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Abstract | Cited by

We have successfully demonstrated a chloride-promoted Pd-catalyzed phosphine-free direct C–H arylation for highly efficient synthesis of high molecular weight π-conjugated polymers. Among halide ions, chloride ions played a crucial role in highly efficient C–H activation.

Graphical abstract: Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers

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