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Issue 33, 2015
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Synthesis and properties of low band gap polymers based on thienyl thienoindole as a new electron-rich unit for organic photovoltaics

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Abstract

A series of polymers based on 6-(2-thienyl)-4H-thieno[3,2-b]indole (TTI), a new electron-rich unit for organic photovoltaics, was synthesized. By replacing the six-membered benzene ring of the carbazole with an electron-rich five-membered thiophene ring, an enhanced ICT effect between the electron-rich group and the electron-deficient group is expected to result in improved π-electron delocalization, low band gap and increased light-harvesting ability of the OPVs. The TTI unit, with a fused rigid backbone, has an efficient structure for the ICT effect and for tuning of the HOMO and LUMO energy levels to generate a low band gap. As electron-deficient units, 4,7-bis(4-hexylthiophen-2-yl)-2,1,3-benzothiadiazole (DTBT-h), 2-dimethyl-4,7-di(2-thienyl)-2H-benzimidazole (DTMBI) and 3,6-di(2-thienyl)-2,5 dihydropyrrolo[3,4-c]pyrrole-1,4-dione (DPP) were introduced by using Stille polymerization. PTTIDTMBI and PTTIDPP have low band gaps and show absorption up to 849 and 948 nm, respectively. The highest PCE was achieved with the device fabricated from a PTTIDTBT-h : PC71BM (1 : 3 w/w) blend with 1,8-octanedithiol (ODT) as an additive. The device demonstrated a Voc value of 0.81 V, a Jsc value of 8.19 mA cm−2, and an FF of 0.51, giving a highest power conversion efficiency of 3.35%.

Graphical abstract: Synthesis and properties of low band gap polymers based on thienyl thienoindole as a new electron-rich unit for organic photovoltaics

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Supplementary files

Article information


Submitted
09 Apr 2015
Accepted
27 Jun 2015
First published
30 Jun 2015

Polym. Chem., 2015,6, 6011-6020
Article type
Paper

Synthesis and properties of low band gap polymers based on thienyl thienoindole as a new electron-rich unit for organic photovoltaics

J. Y. Shim, J. Baek, J. Kim, S. Y. Park, J. Kim, I. Kim, H. H. Chun, J. Y. Kim and H. Suh, Polym. Chem., 2015, 6, 6011
DOI: 10.1039/C5PY00501A

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