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Abstract | Cited by

Thiol-Michael addition polymerization is successfully implemented in a miniemulsion polymerization system. By off-stoichiometric polymerization between thiols and acrylates, inherently functionalized particles are facilely prepared in a single step. We demonstrate that the latex films from such particles are readily available for further modification and second-stage photo-curing.

Graphical abstract: Thiol-Michael addition miniemulsion polymerizations: functional nanoparticles and reactive latex films

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