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A solid polymer electrolyte exhibiting high ionic conductivity (reaching ca. 10−4.8 S cm−1 at 25 °C) is fabricated using ion containing polymer microgels of lithium tris(perfluorophenyl) (2,3,5,6-tetrafluoro-4-(2-(2-(vinyloxy)ethoxy)ethoxy)phenyl) borate. This solid polymer electrolyte shows great possibilities for use in large-capacity lithium ion batteries.

Graphical abstract: Highly efficient solid polymer electrolytes using ion containing polymer microgels

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