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Abstract | Cited by

We report a novel silkworm cocoon-like nanostructure based on the 3D hierarchical self-assembly of cylinders which are spontaneously formed by an H-shaped polymer brush comprising a disulfide-bridged spacer and two brushes with alternating PEG and PCL side chains. Crystalline of PCL between adjacent cylinders bridges cylinders.

Graphical abstract: Silkworm cocoons by cylinders self-assembled from H-shaped alternating polymer brushes

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