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Abstract | Cited by

A visible-light-promoted chloramination of olefins is reported. N-Chlorosulfonamides serve as both nitrogen and chlorine sources. These reactions provide a simple, efficient, regioselective, and atom-economical method for the preparation of vicinal haloamine derivatives under mild reaction conditions. A variety of olefins were tolerated, and chloramination products were obtained in good yields.

Graphical abstract: Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources

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