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Abstract | Cited by

The first direct access to unprotected amino-pyrroloindoline via aminocyclization of tryptamine and tryptophan has been described. A variety of structurally diverse amino-pyrroloindolines are furnished by the use of O-(2,4-dinitrophenyl)hydroxylamine (DPH) as the nitrogen source in the presence of catalytic Rh2(esp)2.

Graphical abstract: Synthesis of naked amino-pyrroloindoline via direct aminocyclization of tryptamine

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