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Issue 19, 2015
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Synthesis of naked amino-pyrroloindoline via direct aminocyclization of tryptamine

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Abstract

The first direct access to unprotected amino-pyrroloindoline via aminocyclization of tryptamine and tryptophan has been described. A variety of structurally diverse amino-pyrroloindolines are furnished by the use of O-(2,4-dinitrophenyl)hydroxylamine (DPH) as the nitrogen source in the presence of catalytic Rh2(esp)2.

Graphical abstract: Synthesis of naked amino-pyrroloindoline via direct aminocyclization of tryptamine

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Publication details

The article was received on 18 Mar 2015, accepted on 10 Apr 2015 and first published on 10 Apr 2015


Article type: Communication
DOI: 10.1039/C5OB00546A
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Citation: Org. Biomol. Chem., 2015,13, 5381-5384
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    Synthesis of naked amino-pyrroloindoline via direct aminocyclization of tryptamine

    Z. Shen, Z. Xia, H. Zhao, J. Hu, X. Wan, Y. Lai, C. Zhu and W. Xie, Org. Biomol. Chem., 2015, 13, 5381
    DOI: 10.1039/C5OB00546A

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