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The combination of (i) the light-harvesting nature and excited-state redox reactivity of a cationic DNA intercalator, (ii) a conjugated Ag+-binding crown ether, and (iii) the stabilizing effect of DNA on AgNPs in one integral ternary complex enables the mild photoinduced formation of Ag nanoparticles.

Graphical abstract: Photoinduced formation of stable Ag-nanoparticles from a ternary ligand-DNA-Ag+ complex

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