The combination of (i) the light-harvesting nature and excited-state redox reactivity of a cationic DNA intercalator, (ii) a conjugated Ag+-binding crown ether, and (iii) the stabilizing effect of DNA on AgNPs in one integral ternary complex enables the mild photoinduced formation of Ag nanoparticles.
D. V. Berdnikova, H. Ihmels, H. Schönherr, M. Steuber and D. Wesner, Org. Biomol. Chem., 2015, 13, 3766 DOI: 10.1039/C5OB00295H
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