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Abstract | Cited by

Heck arylation with allylic alcohol is extremely challenging due to chemo-, regio-, and stereoselective scrambling. Here we report a mild protocol for the alcohol selective β- and α-arylation of allylic and cinnamyl alcohols respectively with aryldiazonium salts. The steric and electronic parameters of the alkene play a prominent role in the regioselectivity.

Graphical abstract: Chemo-, regio-, and stereoselective Heck–Matsuda arylation of allylic alcohols under mild conditions

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