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Abstract | Cited by

Decarboxylative alkylation or acylation reactions of simple pyrimidines have been developed in aqueous media. Using aliphatic carboxylic acids or 2-oxocarboxylic acids and pyrimidines as substrates and silver as the catalyst, the 4-substituted alkyl or acyl pyrimidines were isolated in moderate to good yields.

Graphical abstract: Silver catalysed decarboxylative alkylation and acylation of pyrimidines in aqueous media

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