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Issue 6, 2015
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Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

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Abstract

A concise and diastereoselective route to the angularly fused [5–6–7] tricyclic carbon framework of the steenkrotin-type diterpenoids was reported. The key features of the strategy are based on an intramolecular nitrile oxide/alkene [3 + 2] cycloaddition and a regio-selective aldol/dehydration sequence.

Graphical abstract: Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

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Publication details

The article was received on 20 Nov 2014, accepted on 15 Dec 2014 and first published on 16 Dec 2014


Article type: Communication
DOI: 10.1039/C4OB02439G
Org. Biomol. Chem., 2015,13, 1643-1646

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    Construction of the tricyclic core of steenkrotin-type diterpenoids via intramolecular [3 + 2] cycloaddition

    J. Xuan, S. Pan, Y. Zhang, B. Ye and H. Ding, Org. Biomol. Chem., 2015, 13, 1643
    DOI: 10.1039/C4OB02439G

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