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Issue 2, 2015
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Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

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Abstract

A highly efficient catalytic asymmetric alkynylation of prochiral CH2 groups in tetrahydroisoquinoline was developed using copper catalyzed cross-dehydrogenative-coupling of sp3 and sp C–H bonds with the assistance of a photocatalyst and visible light.

Graphical abstract: Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

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Publication details

The article was received on 07 Oct 2014, accepted on 16 Oct 2014 and first published on 16 Oct 2014


Article type: Paper
DOI: 10.1039/C4OB02138J
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Org. Biomol. Chem., 2015,13, 447-451

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    Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

    I. Perepichka, S. Kundu, Z. Hearne and C. Li, Org. Biomol. Chem., 2015, 13, 447
    DOI: 10.1039/C4OB02138J

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