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Issue 45, 2015
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Tailoring open metal sites for selective capture of CO2 in isostructural metalloporphyrin porous organic networks

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Abstract

Porphyrin-based isostructural porous organic networks have been synthesized by varying the central metal atoms to cobalt, nickel and copper. Their selectivities for CO2 capture over N2 and Ar are found to be enhanced as the heats of adsorption for CO2 are increased in the order of Co, Ni and Cu, while the pore structures are well maintained.

Graphical abstract: Tailoring open metal sites for selective capture of CO2 in isostructural metalloporphyrin porous organic networks

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Article information


Submitted
21 Aug 2015
Accepted
20 Oct 2015
First published
22 Oct 2015

Nanoscale, 2015,7, 18923-18927
Article type
Communication

Tailoring open metal sites for selective capture of CO2 in isostructural metalloporphyrin porous organic networks

H. S. Choi, H. J. Jeon, J. H. Choi, G. Lee and J. K. Kang, Nanoscale, 2015, 7, 18923
DOI: 10.1039/C5NR05696A

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