Issue 11, 2015

Oxoiron(iv)-mediated Baeyer–Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

Abstract

In this communication we describe detailed mechanistic studies on the [FeII(CH3CN)(N4Py)(ClO4)]ClO4-catalyzed (N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methyl-amine) Baeyer–Villiger oxidation of cyclohexanones by dioxygen with cooxidation of various aldehydes, including the kinetics of the formation and the reactivity of the trapped and spectroscopically characterized oxoiron(IV) intermediate.

Graphical abstract: Oxoiron(iv)-mediated Baeyer–Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

Supplementary files

Article information

Article type
Letter
Submitted
06 Aug 2015
Accepted
03 Sep 2015
First published
04 Sep 2015

New J. Chem., 2015,39, 8245-8248

Author version available

Oxoiron(IV)-mediated Baeyer–Villiger oxidation of cyclohexanones generated by dioxygen with co-oxidation of aldehydes

D. Lakk-Bogáth, G. Speier and J. Kaizer, New J. Chem., 2015, 39, 8245 DOI: 10.1039/C5NJ02093J

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