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Issue 9, 2015
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Facile synthesis of unsymmetrical and π-extended furan-diketopyrrolopyrrole derivatives through C–H direct (hetero)arylation using a heterogeneous catalyst system

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Abstract

A mono functionalization of bis-furandiketopyrrolopyrrole (DPPFu2) via direct (hetero)arylation has been developed. This method allows for rapid access to a new family of narrow band-gap, π-extended DPP derivatives via consecutive C–H bond activation between mono-arylated DPP and aryl bromides with heterogeneous catalysts in a simple fashion.

Graphical abstract: Facile synthesis of unsymmetrical and π-extended furan-diketopyrrolopyrrole derivatives through C–H direct (hetero)arylation using a heterogeneous catalyst system

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Article information


Submitted
06 May 2015
Accepted
03 Jun 2015
First published
04 Jun 2015

New J. Chem., 2015,39, 6714-6717
Article type
Letter
Author version available

Facile synthesis of unsymmetrical and π-extended furan-diketopyrrolopyrrole derivatives through C–H direct (hetero)arylation using a heterogeneous catalyst system

J. Areephong, A. D. Hendsbee and G. C. Welch, New J. Chem., 2015, 39, 6714
DOI: 10.1039/C5NJ01150G

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