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Palladium nanoparticles were firstly stabilized with metal–organic framework-derived porous carbon for biofuel upgrade, where the catalyst wettability is crucial. The remarkable catalytic performance of Pd/NPC-ZIF-8 in water can be attributed to the well-dispersed and electron-rich Pd sites, high surface area and hierarchical pores, as well as the favorable hydrophilicity of NPC-ZIF-8.

Graphical abstract: Palladium nanoparticles stabilized with N-doped porous carbons derived from metal–organic frameworks for selective catalysis in biofuel upgrade: the role of catalyst wettability

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