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Issue 1, 2015
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Lignin solubilisation and gentle fractionation in liquid ammonia

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Abstract

We present a simple method for solubilising lignin using liquid ammonia. Unlike water, which requires harsh conditions, ammonia can solubilise technical lignins, in particular kraft lignin. A commercial pine wood Kraft lignin (Indulin AT) was solubilized instantaneously at room temperature and 7–11 bars autogeneous pressure, while a commercial mixed wheat straw/Sarkanda grass soda lignin (Protobind™ 1000) was solubilized within 3 h at ambient temperature, and 30 min at. 85 °C. Hydroxide salts were not required. Wheat straw, poplar and spruce organosolv lignins, as well as elephant grass native lignin (MWL) were also solubilized, albeit at lower values. Different sequences of solubilisation and extraction were tested on the Protobind™ 1000 lignin. The remaining lignin residues were characterized by FTIR, size exclusion chromatography (SEC), elemental analysis (ICP), 2D-NMR and 31P NMR. Liquid ammonia is not an innocent solvent, as some nitrogen was incorporated in the residual lignin which then rearranged to higher molecular weight fractions. Nevertheless, the mild solubilisation conditions make liquid ammonia an attractive candidate as a solvent for lignin in future biorefinery processes.

Graphical abstract: Lignin solubilisation and gentle fractionation in liquid ammonia

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Publication details

The article was received on 18 Jun 2014, accepted on 09 Sep 2014 and first published on 18 Sep 2014


Article type: Paper
DOI: 10.1039/C4GC01143K
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Green Chem., 2015,17, 325-334
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    Lignin solubilisation and gentle fractionation in liquid ammonia

    Z. Strassberger, P. Prinsen, F. V. D. Klis, D. S. V. Es, S. Tanase and G. Rothenberg, Green Chem., 2015, 17, 325
    DOI: 10.1039/C4GC01143K

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