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Issue 9, 2015
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Electrolysis of liquid ammonia for hydrogen generation

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One route to efficient storage, transportation and utilization of renewable hydrogen is through its conversion into ammonia (NH3). In order to examine the feasibility of an NH3 fuel cycle, the electrolysis of NH3 – both as a liquid and dissolved in N,N-dimethylformamide – was investigated using platinum electrodes. The current scaled with electrolyte concentration, but was nominally independent of composition, suggesting solution resistance limitations. NH3 was found to be the chemical species oxidized at the anode which produced N2, but also resulted in a poisoned electrode surface which introduced an additional overpotential of ∼0.5 V. Surprisingly, NH4+ was the species reduced at the cathode via a one-electron transfer process to form Image ID:c5ee01840d-t1.gif, prior to H2 generation, which resulted in an additional cathodic overpotential. In addition to establishing the two half reactions of liquid ammonia electrolysis, the formal potentials of the reactions and the kinetic overpotentials were quantified.

Graphical abstract: Electrolysis of liquid ammonia for hydrogen generation

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Article information

15 Jun 2015
27 Jul 2015
First published
28 Jul 2015

Energy Environ. Sci., 2015,8, 2775-2781
Article type

Electrolysis of liquid ammonia for hydrogen generation

D. J. Little, M. R. Smith, III and T. W. Hamann, Energy Environ. Sci., 2015, 8, 2775
DOI: 10.1039/C5EE01840D

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