Jump to main content
Jump to site search

Issue 10, 2015
Previous Article Next Article

Interfacial band-edge energetics for solar fuels production

Author affiliations


Photoelectrochemical (PEC) water splitting has received growing attention as a potential pathway to replace fossil fuels and produce a clean, renewable, and sustainable source of fuel. To achieve overall water splitting and the associated production of solar fuels, complex devices are needed to efficiently capture light from the sun, separate photogenerated charges, and catalyze reduction and oxidation reactions. To date, the highest performing solar fuels devices rely on multi-component systems, which introduce interfaces that can be associated with further performance loss due to thermodynamic and kinetic considerations. In this review, we identify several of the most important interfaces used in PEC water splitting, summarize methods to characterize them, and highlight approaches to mitigating associated loss mechanisms.

Graphical abstract: Interfacial band-edge energetics for solar fuels production

Back to tab navigation

Publication details

The article was received on 12 Jun 2015, accepted on 12 Aug 2015 and first published on 13 Aug 2015

Article type: Review Article
DOI: 10.1039/C5EE01822F
Author version
Download author version (PDF)
Energy Environ. Sci., 2015,8, 2851-2862

  •   Request permissions

    Interfacial band-edge energetics for solar fuels production

    W. A. Smith, I. D. Sharp, N. C. Strandwitz and J. Bisquert, Energy Environ. Sci., 2015, 8, 2851
    DOI: 10.1039/C5EE01822F

Search articles by author