Two new paramagnetic ionic liquids (ILs) comprising a mononuclear iron(III) or manganese(III) complex cation, charge balanced by a dicyanamide anion are reported which show a range of spin states. Both are liquids at room temperature and the Fe(III) based IL exhibits a spin crossover close to 300 K. The spin crossover profile is independent of the solvation, and is both air and moisture stable.
A. J. Fitzpatrick, H. M. O'Connor and G. G. Morgan, Dalton Trans., 2015, 44, 20839 DOI: 10.1039/C5DT04264J
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