A nickel complex with a biscarbene pincer-type ligand shows high electrocatalytic reduction of CO2 over H2O

Meili Sheng; Nan Jiang; Samantha Gustafson; Bo You; Daniel H. Ess; Yujie Sun

doi:10.1039/C5DT02916C

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A nickel complex with a biscarbene pincer-type ligand shows high electrocatalytic reduction of CO₂ over H₂O†

Meili Sheng,^a Nan Jiang,^a Samantha Gustafson,^b Bo You,^a Daniel H. Ess*^b and Yujie Sun*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, USA
E-mail: yujie.sun@usu.edu
Tel: +1-435-797-7608

^b Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602, USA
E-mail: dhe@byu.edu
Tel: +1-801-422-9164

Abstract

We report a planar nickel complex coordinated with a pincer-type carbene–pyridine–carbene ligand which exhibits high selectivity for electrocatalytic CO₂ reduction in the presence of H₂O.

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Article information

DOI: https://doi.org/10.1039/C5DT02916C
Article type: Communication
Submitted: 29 Jul 2015
Accepted: 12 Aug 2015
First published: 17 Aug 2015

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Dalton Trans., 2015,44, 16247-16250

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A nickel complex with a biscarbene pincer-type ligand shows high electrocatalytic reduction of CO₂ over H₂O

M. Sheng, N. Jiang, S. Gustafson, B. You, D. H. Ess and Y. Sun, Dalton Trans., 2015, 44, 16247 DOI: 10.1039/C5DT02916C

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Dalton Transactions