Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework

Juan Wang; Zhen Wei; Fengwan Guo; Chenyang Li; Pengfei Zhu; Wenhua Zhu

doi:10.1039/C5DT02111A

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Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework†

Juan Wang,

*^a Zhen Wei,^a Fengwan Guo,^b Chenyang Li,^a Pengfei Zhu^a and Wenhua Zhu^a

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* Corresponding authors

^a Hubei Callaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, China
E-mail: wangjuan_hd@163.com
Fax: +86-27-88663043
Tel: +86-27-88662747

^b College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fwg@pku.edu.cn

Abstract

A luminescent homochiral uranyl succinate coordination polymer with unprecedented three-directional helices was synthesized hydrothermally via spontaneous symmetry breaking, and fully characterized. Its homochirality has been confirmed by singe crystal X-ray diffraction and solid state circular dichroism (CD) spectra. The polymer exhibited a Stokes shift greater than 180 nm.

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Article information

DOI: https://doi.org/10.1039/C5DT02111A
Article type: Communication
Submitted: 04 Jun 2015
Accepted: 30 Jun 2015
First published: 30 Jun 2015

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Dalton Trans., 2015,44, 13809-13813

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Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework

J. Wang, Z. Wei, F. Guo, C. Li, P. Zhu and W. Zhu, Dalton Trans., 2015, 44, 13809 DOI: 10.1039/C5DT02111A

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Dalton Transactions

Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework†

Abstract

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Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework

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