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Issue 45, 2015
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Brønsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides

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Abstract

A catalytic 1,2-fluorine migration reaction with simple fluoroepoxides at room temperature is reported. Under Brønsted acid catalysis, α-fluorinated ketones are efficiently constructed in the absence of an external fluorine source through a 1,2-fluorine migration reaction. The experimental results indicate that the present 1,2-fluorine migration reaction proceeds via a carbocation intermediate.

Graphical abstract: Brønsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides

  • This article is part of the themed collection: Fluorine
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Article information


Submitted
03 Jun 2015
Accepted
21 Jul 2015
First published
22 Jul 2015

Dalton Trans., 2015,44, 19636-19641
Article type
Paper

Brønsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides

T. Luo, R. Zhang, X. Shen, W. Zhang, C. Ni and J. Hu, Dalton Trans., 2015, 44, 19636
DOI: 10.1039/C5DT02088C

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