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Issue 45, 2015
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Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)

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Abstract

The first structure of an aromatic bis(trifluoroborate) dipotassium salt, elucidated by the combination of crystallography, DFT calculations, topological and non-covalent interaction analysis, discloses a 3D network undergoing spontaneous self-assembly thanks to the massive participation of weak intra- and intermolecular interactions for which fluorine atoms proved to play a leading role.

Graphical abstract: Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)

  • This article is part of the themed collection: Fluorine
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Publication details

The article was received on 28 May 2015, accepted on 26 Jun 2015 and first published on 26 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT02020D
Dalton Trans., 2015,44, 19447-19450
  • Open access: Creative Commons BY license
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    Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)

    A. Falcicchio, S. O. Nilsson Lill, F. M. Perna, A. Salomone, D. I. Coppi, C. Cuocci, D. Stalke and V. Capriati, Dalton Trans., 2015, 44, 19447
    DOI: 10.1039/C5DT02020D

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