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Issue 34, 2015
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Synthesis of magnesium ZIF-8 from Mg(BH4)2

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Abstract

Porous Mg(2-methyl imidazolate)2 (Mg-ZIF-8) was synthesised from Mg(BH4)2 as a precursor under an Ar atmosphere. It possesses an uncommon tetrahedral Mg2+–N coordination geometry that is stabilised by the formation of a framework, and it exhibits a Brunauer–Emmett–Teller surface area greater than 1800 m2 g−1.

Graphical abstract: Synthesis of magnesium ZIF-8 from Mg(BH4)2

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Article information


Submitted
25 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

Dalton Trans., 2015,44, 15107-15110
Article type
Communication

Synthesis of magnesium ZIF-8 from Mg(BH4)2

S. Horike, K. Kadota, T. Itakura, M. Inukai and S. Kitagawa, Dalton Trans., 2015, 44, 15107
DOI: 10.1039/C5DT01183C

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