Issue 34, 2015
From the journal:

Dalton Transactions

Synthesis of magnesium ZIF-8 from Mg(BH4)2†

S. Horike,*ab   K. Kadota,a   T. Itakura,c   M. Inukaid  and  S. Kitagawaad  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Japan
E-mail: horike@sbchem.kyoto-u.ac.jp

b Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

c DENSO Corporation, 1-1 Showa-cho, Kariya, Aichi 448-8661, Japan

d Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

Porous Mg(2-methyl imidazolate)2 (Mg-ZIF-8) was synthesised from Mg(BH4)2 as a precursor under an Ar atmosphere. It possesses an uncommon tetrahedral Mg2+–N coordination geometry that is stabilised by the formation of a framework, and it exhibits a Brunauer–Emmett–Teller surface area greater than 1800 m2 g−1.

Graphical abstract: Synthesis of magnesium ZIF-8 from Mg(BH4)2

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Article information

DOI
https://doi.org/10.1039/C5DT01183C
Article type
Communication
Submitted
25 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

Dalton Trans., 2015,44, 15107-15110

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Synthesis of magnesium ZIF-8 from Mg(BH4)2

S. Horike, K. Kadota, T. Itakura, M. Inukai and S. Kitagawa, Dalton Trans., 2015, 44, 15107 DOI: 10.1039/C5DT01183C

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