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Issue 34, 2015
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Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

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Abstract

A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O2 evolution reaction using cerium(IV) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O2 evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.

Graphical abstract: Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

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Supplementary files

Article information


Submitted
24 Feb 2015
Accepted
29 Apr 2015
First published
29 Apr 2015

Dalton Trans., 2015,44, 15126-15129
Article type
Communication
Author version available

Regulation of a cerium(IV)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

T. Koshiyama, N. Kanda, K. Iwata, M. Honjo, S. Asada, T. Hatae, Y. Tsuji, M. Yoshida, M. Okamura, R. Kuga, S. Masaoka and M. Ohba, Dalton Trans., 2015, 44, 15126
DOI: 10.1039/C5DT00793C

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