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Issue 24, 2015
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Structure and magnetic properties of an unusual homoleptic iron(iii) thiocyanate dimer

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Abstract

We describe the structural and variable temperature magnetic susceptibility properties of an unusual homoleptic bimetallic iron(III) thiocyanate tetraanion. This work represents the first structurally characterized bis(μ-1,3-thiocyanato) dimer of iron(III). A weak antiferromagnetic exchange interaction is observed between the two iron(III) ions, which is supported by broken symmetry density functional theory (DFT) calculations.

Graphical abstract: Structure and magnetic properties of an unusual homoleptic iron(iii) thiocyanate dimer

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Article information


Submitted
19 Feb 2015
Accepted
12 May 2015
First published
13 May 2015

Dalton Trans., 2015,44, 11077-11082
Article type
Paper

Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

D. R. Dinsdale, A. J. Lough and M. T. Lemaire, Dalton Trans., 2015, 44, 11077
DOI: 10.1039/C5DT00743G

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