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Issue 16, 2015
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Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

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Abstract

Two dysprosium complexes, [(C5H4Me)2Dy(L1)] (3) and [(L1)Dy(μ-Cl)3{Li(tmeda)}]2 (4), with amino-functionalized pentadienyl ligands L1 are described. Crystallographic studies of 3 and 4 show that the pendant amino group influences the pentadienyl conformation and the ligand hapticity. Electronic structure calculations reveal that L1 has a strong influence on the orientation of the main magnetic axis of the ground Kramers doublets in 3 and 4.

Graphical abstract: Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

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Supplementary files

Article information


Submitted
26 Jan 2015
Accepted
03 Mar 2015
First published
04 Mar 2015

Dalton Trans., 2015,44, 7109-7113
Article type
Communication
Author version available

Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

B. M. Day, N. F. Chilton and R. A. Layfield, Dalton Trans., 2015, 44, 7109
DOI: 10.1039/C5DT00346F

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