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Issue 27, 2015
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Ring-opening polymerization of cyclohexene oxide using aluminum amine–phenolate complexes

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Abstract

Remarkably active (down to 0.001% Al) catalysts for ring-opening polymerization of cyclohexene oxide under neat reaction conditions are reported. High molecular weight polymers with uniform dispersity are produced. Kinetic data from NMR studies and MALDI-TOF MS data of the polymers provide some mechanistic insight.

Graphical abstract: Ring-opening polymerization of cyclohexene oxide using aluminum amine–phenolate complexes

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Supplementary files

Article information


Submitted
16 Jan 2015
Accepted
10 Feb 2015
First published
11 Feb 2015

This article is Open Access

Dalton Trans., 2015,44, 12098-12102
Article type
Communication
Author version available

Ring-opening polymerization of cyclohexene oxide using aluminum amine–phenolate complexes

H. Plommer, I. Reim and F. M. Kerton, Dalton Trans., 2015, 44, 12098
DOI: 10.1039/C5DT00220F

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