Issue 12, 2015
From the journal:

Dalton Transactions

Intramolecular N-coordination in ketiminoboranes†‡

Catherine E. Bacon,a   Liz Mansour,b   John J. Haywardb  and  Jeremy M. Rawson*b  

* Corresponding authors

a Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

b Department of Chemistry & Biochemistry, The University of Windsor, 401 Sunset Avenue, Windsor, Ontario, Canada N9B 3P4
E-mail: jmrawson@uwindsor.ca

Abstract

Treatment of the imine PhC([double bond, length as m-dash]NSiMe3)py with Et2BOMe or BF3·Et2O afforded bicyclic ketiminoboranes 4a and 4bvia intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of 4a·HCl and 4b·BF3 are reported as well as the dipyridyl imine derivative 4c·HCl.

Graphical abstract: Intramolecular N-coordination in ketiminoboranes

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Article information

DOI
https://doi.org/10.1039/C5DT00196J
Article type
Communication
Submitted
15 Jan 2015
Accepted
13 Feb 2015
First published
16 Feb 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 5284-5287

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Intramolecular N-coordination in ketiminoboranes

C. E. Bacon, L. Mansour, J. J. Hayward and J. M. Rawson, Dalton Trans., 2015, 44, 5284 DOI: 10.1039/C5DT00196J

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