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Issue 12, 2015
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Intramolecular N-coordination in ketiminoboranes

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Treatment of the imine PhC([double bond, length as m-dash]NSiMe3)py with Et2BOMe or BF3·Et2O afforded bicyclic ketiminoboranes 4a and 4bvia intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of 4a·HCl and 4b·BF3 are reported as well as the dipyridyl imine derivative 4c·HCl.

Graphical abstract: Intramolecular N-coordination in ketiminoboranes

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The article was received on 15 Jan 2015, accepted on 13 Feb 2015 and first published on 16 Feb 2015

Article type: Communication
DOI: 10.1039/C5DT00196J
Citation: Dalton Trans., 2015,44, 5284-5287
  • Open access: Creative Commons BY license
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    Intramolecular N-coordination in ketiminoboranes

    C. E. Bacon, L. Mansour, J. J. Hayward and J. M. Rawson, Dalton Trans., 2015, 44, 5284
    DOI: 10.1039/C5DT00196J

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