Issue 27, 2015

Alkali metal-mediated dehydrocoupling of Me2NH·BH3

Abstract

Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N] anions.

Graphical abstract: Alkali metal-mediated dehydrocoupling of Me2NH·BH3

Supplementary files

Article information

Article type
Communication
Submitted
14 Jan 2015
Accepted
09 Mar 2015
First published
13 Mar 2015

Dalton Trans., 2015,44, 12078-12081

Author version available

Alkali metal-mediated dehydrocoupling of Me2NH·BH3

P. Bellham, M. S. Hill and G. Kociok-Köhn, Dalton Trans., 2015, 44, 12078 DOI: 10.1039/C5DT00178A

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