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Issue 27, 2015
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Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

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Abstract

Two cobalt compounds, Cp*Co(CO)I2 (1) and CpCo(CO)I2 (2) (Cp* = η5-C5Me5, Cp = η5-C5H5), catalyze the dehydrogenation of ammonia borane under either anaerobic or aerobic conditions and are also effective hydrogenation catalysts for alkenes and alkynes using ammonia borane as a hydrogen source, also in the presence of air.

Graphical abstract: Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

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Supplementary files

Article information


Submitted
09 Jan 2015
Accepted
24 Feb 2015
First published
25 Feb 2015

Dalton Trans., 2015,44, 12074-12077
Article type
Communication

Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

J. K. Pagano, J. P. W. Stelmach and R. Waterman, Dalton Trans., 2015, 44, 12074
DOI: 10.1039/C5DT00108K

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