Jump to main content
Jump to site search

Issue 34, 2015
Previous Article Next Article

A 2,2′-bipyridine coordination complex of [ICl2]+

Author affiliations

Abstract

The formation of a new class of I(III) compound is reported; an N,N′ chelated iodine cation ([bpy-ICl2]+; bpy = 2,2′-bipyridine). The complex is obtained as an [ICl4] salt and is formed via simple reaction of bpy with ICl3. The compound is relatively unstable, but may be stored as a solid and is shown to be competent in the oxidative chlorination of Au(I)-NHC complexes.

Graphical abstract: A 2,2′-bipyridine coordination complex of [ICl2]+

Back to tab navigation

Supplementary files

Article information


Submitted
07 Nov 2014
Accepted
24 Nov 2014
First published
24 Nov 2014

Dalton Trans., 2015,44, 15083-15087
Article type
Communication
Author version available

A 2,2′-bipyridine coordination complex of [ICl2]+

A. J. M. Shaw, R. Corbo, D. J. D. Wilson and J. L. Dutton, Dalton Trans., 2015, 44, 15083
DOI: 10.1039/C4DT03549F

Social activity

Search articles by author

Spotlight

Advertisements