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Issue 7, 2015
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Synthesis, structure, and properties of a dialumane supported by pyrazolate ligands

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Abstract

The dialumane [Al2][Na(Ph2pz)3]2 (1) has been prepared by the reaction of Na(Ph2pz) with a metastable solution of AlCl. The structure of 1 contains two hydrotris(pyrazolyl)borate-like Na(Ph2pz)32− moieties that are coordinated to each Al atom of the dialumane in a κ21-N,N,N fashion and several π-stacking interactions are present between the pyrazolate and phenyl rings. In solution the pyrazolate ligands in 1 are in dynamic exchange, even at −80 °C, which shows the lability of these ligands to the low-valent aluminum centers.

Graphical abstract: Synthesis, structure, and properties of a dialumane supported by pyrazolate ligands

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Supplementary files

Article information


Submitted
17 Nov 2014
Accepted
09 Dec 2014
First published
11 Dec 2014

Dalton Trans., 2015,44, 2956-2958
Article type
Communication

Synthesis, structure, and properties of a dialumane supported by pyrazolate ligands

C. J. Snyder, P. Zavalij, K. Bowen, H. Schnöckel and B. Eichhorn, Dalton Trans., 2015, 44, 2956
DOI: 10.1039/C4DT03533J

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