The initial employment of a triketone ligand in 4f coordination chemistry afforded a series of dinuclear complexes. Magnetic studies revealed that an antiferromagnetic interaction exists in a digadolinium(III) compound, while a dysprosium(III) constructed complex exhibits single-molecule magnet (SMM) behaviour at low temperatures with an energy barrier of 86.8 K.
C. Wang, S. Lin, J. Wu, S. Yuan and J. Tang, Dalton Trans., 2015, 44, 4648 DOI: 10.1039/C4DT03494E
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