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Issue 10, 2015
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Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

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Abstract

A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature. No additional oxidizing agent, base, or phosphine ligands are required.

Graphical abstract: Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

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Article information


Submitted
13 Nov 2014
Accepted
02 Feb 2015
First published
02 Feb 2015

Dalton Trans., 2015,44, 4759-4764
Article type
Paper
Author version available

Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

L. Yong, M. Yao, D. W. Blevins and G. W. Kabalka, Dalton Trans., 2015, 44, 4759
DOI: 10.1039/C4DT03492A

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