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Issue 19, 2015
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Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

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Abstract

Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

Graphical abstract: Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

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Supplementary files

Article information


Submitted
21 Oct 2014
Accepted
03 Dec 2014
First published
06 Jan 2015

Dalton Trans., 2015,44, 8781-8783
Article type
Communication

Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

A. Nordheider, K. S. Athukorala Arachchige, A. M. Z. Slawin, J. D. Woollins and T. Chivers, Dalton Trans., 2015, 44, 8781
DOI: 10.1039/C4DT03257H

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