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Issue 34, 2015
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Abrupt two-step and symmetry breaking spin crossover in an iron(iii) complex: an exceptionally wide [LS–HS] plateau

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Abstract

[Fe(qsal-Br)2]NO3·2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T½(1st step) = 136 K and T½(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS–LS] plateau of 96 K.

Graphical abstract: Abrupt two-step and symmetry breaking spin crossover in an iron(iii) complex: an exceptionally wide [LS–HS] plateau

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Article information


Submitted
16 Oct 2014
Accepted
17 Nov 2014
First published
18 Nov 2014

Dalton Trans., 2015,44, 15079-15082
Article type
Communication
Author version available

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS–HS] plateau

D. J. Harding, W. Phonsri, P. Harding, K. S. Murray, B. Moubaraki and G. N. L. Jameson, Dalton Trans., 2015, 44, 15079
DOI: 10.1039/C4DT03184A

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