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Issue 39, 2015
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Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

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Abstract

Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono–ligated complex has been demonstrated.

Graphical abstract: Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

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Publication details

The article was received on 13 Mar 2015, accepted on 29 May 2015 and first published on 29 May 2015


Article type: Communication
DOI: 10.1039/C5CP01501D
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Phys. Chem. Chem. Phys., 2015,17, 25689-25692

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    Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

    M. Katari, E. Payen de la Garanderie, E. Nicol, V. Steinmetz, G. van der Rest, D. Carmichael and G. Frison, Phys. Chem. Chem. Phys., 2015, 17, 25689
    DOI: 10.1039/C5CP01501D

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