We report herein the vibrational spectroscopic characterisation of a catalytic intermediate formed by the reaction of H2O2 with DyP-type peroxidase immobilised on a biocompatible coated metal support. The SERR spectroscopic approach is of general applicability to other peroxidases which form relatively stable catalytic intermediates.
S. Todorovic, P. Hildebrandt and L. O. Martins, Phys. Chem. Chem. Phys., 2015, 17, 11954 DOI: 10.1039/C5CP01283J
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