A single-crystal to single-crystal phase transition in [Co(NH3)5NO2]Br2 at high pressure: a step towards understanding linkage photo-isomerisation

B. A. Zakharov; A. S. Marchuk; E. V. Boldyreva

doi:10.1039/C5CE01820J

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A single-crystal to single-crystal phase transition in [Co(NH₃)₅NO₂]Br₂ at high pressure: a step towards understanding linkage photo-isomerisation†

B. A. Zakharov,*^ab A. S. Marchuk^ab and E. V. Boldyreva*^ab

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* Corresponding authors

^a Institute of Solid State Chemistry and Mechanochemistry SB RAS, Kutateladze Street 18, Novosibirsk, Russian Federation
E-mail: b.zakharov@yahoo.com

^b Novosibirsk State University, Pirogova Street 2, Novosibirsk, Russian Federation

Abstract

Changes in the crystal structure of [Co(NH₃)₅NO₂]Br₂ – including a previously unknown single-crystal to single-crystal phase transition above 6.0 GPa – were followed from ambient pressure to 6.9 GPa and discussed in relation to the structural mechanism of homogeneous linkage photoisomerisation that is accompanied by photomechanical effects in the same compound.

This article is part of the themed collection: Single-Crystal-to-Single-Crystal Transformations

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Article information

DOI: https://doi.org/10.1039/C5CE01820J
Article type: Communication
Submitted: 11 Sep 2015
Accepted: 24 Oct 2015
First published: 26 Oct 2015

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CrystEngComm, 2015,17, 8812-8816

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A single-crystal to single-crystal phase transition in [Co(NH₃)₅NO₂]Br₂ at high pressure: a step towards understanding linkage photo-isomerisation

B. A. Zakharov, A. S. Marchuk and E. V. Boldyreva, CrystEngComm, 2015, 17, 8812 DOI: 10.1039/C5CE01820J

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