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Issue 30, 2015
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Porous organic hydrate crystals: structure and dynamic behaviour of water clusters

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Abstract

4-Nitrostyrylpyridine hydrochloride forms porous crystals stabilized by cation–π and NO2⋯Cl interactions that involve water clusters with a T5(2) motif in the channels. The crystals reversibly release and re-uptake water molecules. Solid-state 17O NMR spectroscopic analyses revealed the behaviour of the water molecules present in the channels.

Graphical abstract: Porous organic hydrate crystals: structure and dynamic behaviour of water clusters

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Article information


Submitted
24 Dec 2014
Accepted
25 Jun 2015
First published
26 Jun 2015

CrystEngComm, 2015,17, 5629-5633
Article type
Communication

Porous organic hydrate crystals: structure and dynamic behaviour of water clusters

S. Yamada, N. Sako, K. Yamada, K. Deguchi and T. Shimizu, CrystEngComm, 2015, 17, 5629
DOI: 10.1039/C4CE02517B

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