Issue 7, 2016
From the journal:

Chemical Communications

A homochiral vanadium–salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation†

Asamanjoy Bhunia,a   Subarna Dey,b   José María Moreno,c   Urbano Diaz,c   Patricia Concepcion,c   Kristof Van Hecke,d   Christoph Janiakb  and  Pascal Van Der Voort ORCID logo *a  

* Corresponding authors

a Department of Inorganic and Physical Chemistry, Center for Ordered Materials, Organometallics and Catalysis, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium
E-mail: pascal.vandervoort@ugent.be

b Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, 40204 Düsseldorf, Germany

c Instituto de Tecnología Quimica (UPV-CSIC), Avenida de los Naranjos s/n, 46022 Valencia, Spain

d Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

Abstract

A homochiral vanadium–salen based MOF with the pcu topology is constructed via in situ synthesis under solvothermal conditions. The synthesized MOF exhibits BET surface areas of 574 m2 g−1, showing the highest H2 adsorption capacity (1.05 wt% at 77 K, 1 bar) and the highest CO2 uptake (51 cm3 g−1 at 273 K, 1 bar) for currently known salen-based MOFs. This framework shows excellent performance as an asymmetric catalyst in solvent-free cyanosilylation.

Graphical abstract: A homochiral vanadium–salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation

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Article information

DOI
https://doi.org/10.1039/C5CC09459C
Article type
Communication
Submitted
15 Nov 2015
Accepted
18 Nov 2015
First published
19 Nov 2015

Chem. Commun., 2016,52, 1401-1404

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A homochiral vanadium–salen based cadmium bpdc MOF with permanent porosity as an asymmetric catalyst in solvent-free cyanosilylation

A. Bhunia, S. Dey, J. M. Moreno, U. Diaz, P. Concepcion, K. Van Hecke, C. Janiak and P. Van Der Voort, Chem. Commun., 2016, 52, 1401 DOI: 10.1039/C5CC09459C

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