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Issue 92, 2015
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A metal-mediated boron-centred isomerisation reaction via C–H activation

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Abstract

A heterocyclic manganese complex (4) derived from a carbonyl–borylene coupling reaction undergoes isomerisation, during which the former borylene moiety migrates to the cyclopentadienyl ligand and inserts into a C–H bond. This reaction and a computational study of its mechanism are discussed.

Graphical abstract: A metal-mediated boron-centred isomerisation reaction via C–H activation

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Article information


Submitted
15 Sep 2015
Accepted
22 Sep 2015
First published
30 Sep 2015

Chem. Commun., 2015,51, 16569-16572
Article type
Communication

A metal-mediated boron-centred isomerisation reaction via C–H activation

H. Braunschweig, J. O. C. Jimenez-Halla, K. Radacki and R. Shang, Chem. Commun., 2015, 51, 16569
DOI: 10.1039/C5CC07681A

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