Issue 95, 2015

Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

Abstract

A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as sources of the reactive Pt(PMe2ArDipp2) fragment. The complexes are efficient catalysts for the selective hydrosilylation of terminal alkynes.

Graphical abstract: Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

Supplementary files

Article information

Article type
Communication
Submitted
03 Sep 2015
Accepted
25 Sep 2015
First published
28 Sep 2015

Chem. Commun., 2015,51, 17008-17011

Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

L. Ortega-Moreno, R. Peloso, C. Maya, A. Suárez and E. Carmona, Chem. Commun., 2015, 51, 17008 DOI: 10.1039/C5CC07308A

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