The chiral selectivities were altered and high diastereo- and enantio-selectivities of the products were obtained in water medium without adding acid co-catalysts when a primary–tertiary diamine catalyst was immobilized on mesoporous SBA-15 to form a recyclable catalyst for the direct asymmetric aldol reaction of cyclohexanone with p-nitrobenzaldehyde.
C. Yeh, Y. Sun, S. Huang, Y. Tsai and S. Cheng, Chem. Commun., 2015, 51, 17116 DOI: 10.1039/C5CC07255G
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