A. Y. Tesio, D. Blasi, M. Olivares-Marín, I. Ratera, D. Tonti and J. Veciana
Chem. Commun., 2015,51, 17623-17626
DOI:
10.1039/C5CC07242E,
Communication
We examine for the first time the ability of inert carbon free-radicals as soluble redox mediators to catalyze and enhance the oxygen reduction reaction in a (TEGDME)-based electrolyte. We demonstrate that the tris(2,4,6-trichlorophenyl)methyl (TTM) radical is capable of chemically favoring the oxygen reduction reaction improving significantly the Li–O2 battery performance.