Two flexible multivalent molecular units are employed to self-assemble highly regular supramolecular porous networks at the solid/liquid interface. Scanning tunnelling microscopy imaging corroborated with molecular dynamics simulations make it possible to elucidate the conformational freedom behind the binding motif, which identify the architecture as a highly regular soft network.
C. Palma, A. Ciesielski, M. A. Öner, G. Schaeffer, J. Lehn, J. V. Barth and P. Samorì, Chem. Commun., 2015, 51, 17297 DOI: 10.1039/C5CC07204B
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